Structural and Optical Study of Lithium Doped Sulphur Supported Reduced Graphene Oxide (LiX:S-rGO1-X) (0.4≤X≤0.6) Composite Electrode for Optoelectronics Applications

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M. Alpha
Idris .M. Bako
A. Z. Ngari
T.O. Daniel
Umar M. Muhammad
Muhammad Ja'afar
Idris .A. Sulaimon

Abstract

The goal of this study was to developed a conducting Lithium doped sulfur supported reduced graphene oxide composites using hydrothermal reduction technique approach that allows the presence of different weight concentration of Li ion in network of supported reduced graphene oxide for application as electrode material. Scanning electron microscopy, X-ray diffraction, and UV Spectrometry analysis were each used to evaluate the produced composites. From the findings, it was possible to predict that the presence of a nano-size additive Li in the network of the S-rGO composite significantly improve the charge transport and dielectric characteristics of the material at the percolation threshold. The optical energy band gaps for S-rGO, Li0.4:S-rGO0.6, and Li0.6:S-rGO0.4 are, respectively, 3.4 eV, 3.5 eV, and 3.6 eV. These values are optimal and favour achieving the threshold voltage for optoelectronic and energy storage application.


 


 

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How to Cite
Alpha, M., Bako, I. M., A. Z. Ngari, T.O. Daniel, Muhammad, U. M., Ja’afar, M., & Sulaimon, I. A. (2022). Structural and Optical Study of Lithium Doped Sulphur Supported Reduced Graphene Oxide (LiX:S-rGO1-X) (0.4≤X≤0.6) Composite Electrode for Optoelectronics Applications. African Journal of Advances in Science and Technology Research, 8(1), 22–31. Retrieved from https://publications.afropolitanjournals.com/index.php/ajastr/article/view/287
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Articles
Author Biographies

M. Alpha, Nigerian Army University Biu, Borno, Nigeria

Department of Physics,

Nigerian Army University Biu, Borno, Nigeria

 

 

Idris .M. Bako, Nigerian Army University Biu, Borno, Nigeria.

Department of Physics,

Nigerian Army University Biu, Borno, Nigeria.

 

A. Z. Ngari, Nigerian Army University Biu, Borno, Nigeria.

Department of Physics,

Nigerian Army University Biu, Borno, Nigeria.

 

T.O. Daniel, Alex Ekwueme Federal University Ndufu-Alike, Ebonyi State, Nigeria.

Department of Physics,

Alex Ekwueme Federal University Ndufu-Alike, Ebonyi State, Nigeria.

 

Umar M. Muhammad, Nigerian Army University Biu, Borno, Nigeria.

Department of Physics,

Nigerian Army University Biu, Borno, Nigeria.

 

Muhammad Ja'afar, Nigerian Army University Biu, Borno, Nigeria.

Department of Physics,

Nigerian Army University Biu, Borno, Nigeria

 

Idris .A. Sulaimon, Nigerian Army University Biu, Borno, Nigeria.

Department of Physics,

Nigerian Army University Biu, Borno, Nigeria

 

References

Alpha, M., Uno, U.E., Isah, K.U. and Ahmadu. (2019). Structural and Electrochemical Properties of AgxSnO1-x/G (0.3≤x≤0.4) Composite Electrode. European Journal of Scientific Research. 15, 14, 479-488

Daniel, T.O Uno, E.U., Isah, K.U. and Ahmadu, U. (2020). Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor Application. East European Journal of Physics, (2), 94-103

Deshmukh, G.D., Patil, S.M. and Pawar, P.H. (2015). Optical properties of thin Bi2Te3 films synthesized by different techniques. Journal of Chemical, Biological and Physical Sciences, 5, 2769.

Ilican, I., Caglar, Y. and Caglar, M. (2008). Preparation and characterization of ZnO thin films deposited by sol-gel spin coating method. Journal of Optoelectronics and Advanced Materials, 10 (200), 2578.

Jeyaprakash, B.G., Ashok, K.R., Kesavan, K and Amalarani, A. (2010). Synthesis and Some of Structural Characterisation of Nano Particles CdO Thin Film. American Journal of Science, 6

Kasap, S. and Capper, P. (2017) Handbook of electronic and photonic materials. Springer, Berlin 2nd edition

Largeot, J.C., Portet, C., Chmiola, J., Taberna, P.L., Gogotsi, Y. and Simon, P. (2008). Confinement, desolvation and electrosorption effects on the diffusion of ions innanoporous carbon electrode. Journal of American Chemical Society. 130, 2730.

Nakazawa, K., Itoh, S., Matsunaga, T., Matsukawa, Y., Satoh, Y. and Abe, H. (2014). Effect of dislocation and grain boundary on deformation mechanism in ultrafine- graine interstitial- free steel. Material Science and Engineering. 63, 012125

Martinelli, A., Palenzona, A., Putti, M. and Ferdeghini, C. (2009). Microstructural transition in 1111 Oxy-Pnictides. J.W.Lynn, Pengcheng Dai Physica. C469.

Mukherjee, A. and Mitra, P. (2015). Structural and optical characterisation of SnS thin film prepared by SILAR. Material Science-Poland, 33, 847. https://doi.org/10.1515/msp-2005-0118

Pandolfo, A.G. and Hollenkamp, A.F. (2006). Carbon properties and their role in supercapacitors. Journal of Power Sources.; 11, 157-160.

Rajyalakshmi, T., Pasha, A., Khasim, S., Lakshmi, M. and Imran, M. (2020). Synthesis, characterization and Hall‑effect studies of highly conductive polyaniline/graphen nanocomposites. Applied Sciences (2020) 2:530. https://doi.org/10.1007/s42452-020-2349-4

Siamak, P.J., Alagarsamy, P., Boon, T.G., Hong, N.L. and Nay, M.H. (2015). Influence of particle size on performance of Nickel nanoparticles-based supercapacitor. RSC Advances. 5, 14010- 14019.

Skoog, D.A., West, D.M., Holler, F.J. and Crouch, S.R. (2016). Principles of Instrumental Analysis, Seventh Edition. USA: Cengage Learning.

Uwe, H. and Neil, G. (2011). The Scherrer equation versus the Debye-Scherrer Equation. Nature Nanotechnology, 6, 534